Mr. Sunak said it was "deeply humbling" to be in Kyiv and that the UK would continue to stand by Ukraine.
"Since the first days of the war, Ukraine and the UK have been the strongest of allies," Mr. Zelensky said following the meeting.
The aid package is intended to counter Russian aerial attacks.
The £50m defense aid comprises 125 anti-aircraft guns and technology to counter deadly Iranian-supplied drones, including dozens of radars and anti-drone electronic warfare capability.
Mr. Sunak also announced the UK will increase the training offered to Ukraine's armed forces, sending expert army medics and engineers to the region to offer specialized support.
It follows more than 1,000 new anti-air missiles announced by the UK's Defence Secretary Ben Wallace earlier this month.
On his visit, the prime minister saw captured Iranian-made drones which have been used to target and bomb Ukrainian civilians in recent months.
Mr. Sunak also laid flowers for the war dead and lit a candle at a memorial for victims of the 1930s Holodomor famine, before meeting emergency workers at a fire station.
The prime minister said: "I am proud of how the UK stood with Ukraine from the very beginning. And I am here today to say the UK and our allies will continue to stand with Ukraine, as it fights to end this barbarous war and deliver a just peace.
"While Ukraine's armed forces succeed in pushing back Russian forces on the ground, civilians are being brutally bombarded from the air.
We are today providing new air defense, including anti-aircraft guns, radar, and anti-drone equipment, and stepping up humanitarian support for the cold, hard winter ahead.
He added that it was "deeply humbling" to be in the Ukrainian capital and have the opportunity to meet people "paying so high a price, to defend the principles of sovereignty and democracy".
Mr. Sunak's pledge to send more air defense support is exactly what President Zelensky would want to hear at a time when Russian airstrikes have destroyed nearly 50% of the country's energy infrastructure, according to the government in Kyiv.
The men's hopes for peace and a just outcome to the conflict may feel like distant prospects, but Mr. Sunak's promise to hold a reconstruction conference for Ukraine next year in London will be good news for the government and companies, which desperately need access to international finance.
During the visit, Mr. Sunak also confirmed £12m for the World Food Programme's response to Ukraine, as well as £4m for the International Organisation for Migration.
Downing Street said the funding would help provide generators and mobile health clinics, with the UK also sending tens of thousands of extremely cold winter kits for Ukrainian troops.
Labour's shadow defense secretary John Healey tweeted: "The government continues to have Labour's fullest backing to support Ukraine, reinforce Nato allies and confront Russia's aggression."
Ukraine has been requesting assistance from Western nations in recent months amid intense Russian aerial attacks on Kyiv and across the country.
Earlier in the week, Russia hit Ukraine with one of its biggest barrages of missiles yet, days after its troops were forced to withdraw from Kherson.
Kyiv was hit and there were strikes across the country, from Lviv in the west to Chernihiv in the north.
That attack coincided with the G20 summit in Indonesia this week where, in a virtual speech, Mr. Zelensky said he was "convinced now is the time when the Russian destructive war must and can be stopped".
While Mr. Sunak was at the Bali summit, which was attended by Russia's foreign minister Sergei Lavrov, the UK prime minister urged Russia to "get out of Ukraine" and condemned the country for its "barbaric invasion".
He stressed the UK would "back Ukraine for as long as it takes".
Britain is currently the largest provider of military aid to Ukraine aside from the US. So far the UK has committed about £2.3bn and has pledged to match that amount in 2023, according to the House of Commons library.
The UK is also hosting a program that will aim to train 10,000 new and existing Ukrainian personnel within 120 days.
Mr. Sunak's predecessor Boris Johnson previously met Mr. Zelensky in Kyiv in June and August, and Liz Truss was also a vocal supporter of Ukraine.
Mr. Johnson became almost a cult figure in Ukraine after he was one of the first international figures to publicly support Ukraine and send military assistance.
It is a tough comparison for Mr. Sunak to live up to so early on in his premiership. Many people in Ukraine do not know the new prime minister well and they will want to see how committed he is to support the country.
source(BBC)
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